The absorption of light by a sample (gas, liquid, solid) causes the sample to heat up; if the pump light is modulated, this produces a sequence of gas heating and cooling, leading to the generation of thermal and acoustic (sound) waves. Quartz Enhanced Photo-Acoustic Spectroscopy (QEPAS) and Photo-Thermal Spectroscopy (PTS) are ultra-sensitive techniques based on the detection of these acoustic and thermal waves. In QEPAS, a quartz tuning fork is used to detect the acoustic waves created in a gas sample, and is immune to external acoustic noise. PTS detects the refractive index change caused by the absorption-induced heating, using a Fabry-Pérot interferometer. Both techniques can potentially detect extremely low concentrations, at parts per trillion levels or less. PTS can also be applied to liquid sensing and, in combination with Atomic Force Microscopy (AFM), to near-field IR imaging.

The gases which can be detected by QEPAS and PTS depend on the pump laser used, the wavelength of which must be tailored to the absorption lines of the target gas. In order to realise compact, portable and low-cost sensors, these lasers need to have the small footprint of semiconductor lasers, similar to those used in e.g. the telecoms industry, and be closely integrated with the QEPAS/PTS cell. OPTAPHI will develop new hybrid photonic crystal lasers, long wavelength quantum cascade lasers, and III-V lasers grown on silicon, with new wavelength locking mechanisms and analysis techniques, to greatly reduce system size and improve robustness of the optical sensors. Regarding near-field IR imaging it will also conceive new transducers for simultaneously detecting thermal and chemical properties of solid samples with nanometre resolution.